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Polymer Chemical Physics

PCP team

Patrick Navard, Tatiana Budtova, Edith Peuvrel-Disdier



Solutions, suspensions, blends, gels and other complex structures based on polymers are systems with organisation strongly depending on many physical and mechanical parameters. Polymer processing and material final properties are directly linked to the characteristics of these organisations.

 

The study of these complex polymer materials, of their organisational, physical and rheological properties have interdisciplinary challenges (biology for bio-based materials, thermodynamics, physics, chemical-physics and mechanics); they are the main research expertise of the group.

The research activities of the Polymer Chemical Physics (PCP) group can be divided into 3 main areas:

 

1.

 

Cellulose and cellulose-based materials

CCellulose is the most abundant polymer on Earth. As all polysaccharides, it offers an interesting alternative to oil-based polymers owing to its good carbon print performance and its biodegradability.
The research objectives are the understanding of dissolution and swelling mechanisms of cellulose coming from different sources and treated in various ways, the studies of solution thermodynamics and rheology of solutions and cellulose regeneration and processing and the preparation of new materials.
 
aérogel de cellulose pure
Morphology of Aerocellulose : new ultra-light (0.1 g/cm 3) and highly porous (> 95%) pure cellulose « aerogel ».
       

2.

 

Bio-based polymers and bioplastics blends


The research objectives are the understanding, control and prediction of the formation of different morphologies and structures that appear under flow of incompatible bio-based polymer blends in order to vary and improve the properties of final products.
All studied blends include one or several bio-based components (starch, PLA, PHA, cellulose derivatives).
 
Bio-based polymers
Co-continuous structure of an incompatible bio-based polymer blend: PLA/PHA
       

3.

 

Filled polymers and composites


The studied filled systems are very diverse, like suspensions of nano-fillers, of agglomerates, of starch granules and of synthetic micro-gels as well as composites reinforced by plant fibers in various matrices (thermoplastic polymers or lignin).
The research objectives are to understand the behavior of these fillers under flow, the elementary mechanisms for their dispersion, structuration and de-structuration of fillers under flow and to relate this information to the rheological behavior of the filled materials to their processing and final properties.
 
rotation d'un agglomérat de noir de carbone

rupture agglomérat de noir de carbone

séparation agglomérat de noir de carbone
Rupture mechanism of a carbon black agglomerate in an elastomer matrix under shear

In the last two domains, rheology and rheo-optics are major tools to study morphology evolution during flow
 
B.P. 207 - 06904 Sophia Antipolis Cedex
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